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- W2044352812 abstract "The rates of gas-phase thermal elimination reaction of esters of 2-pyridine sulfonic acid and 8-quinoline sulfonic acid have been measured over at least 50° for each compound. The relative rates of the first-order unimolecular decomposition at 500 K for the primary:secondary esters suggest that CO bond breaking is kinetically more significant than CH bond breaking, leading to a transition state of carbocationic character. This is consistent with the electron-donating effect provided by the methoxy substituent in 2-p-methoxyphenylethyl of 2-pyridine and 8-quinoline sulfonate esters stabilizing the carbocation center. © 2000 John Wiley & Sons, Inc. Int J Chem Kinet 32: 771–775, 2000" @default.
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- W2044352812 date "2000-01-01" @default.
- W2044352812 modified "2023-09-26" @default.
- W2044352812 title "Gas-phase pyrolytic reactions of esters of 2-pyridine and 8-quinoline sulfonic acid" @default.
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- W2044352812 doi "https://doi.org/10.1002/1097-4601(2000)32:12<771::aid-kin4>3.0.co;2-0" @default.
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