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- W2044354328 abstract "Existing work on gas-solid reactions making use of thin film technologies is reviewed. The discussion concentrates on two major areas of gas-metal interactions: chemisorption and the early stages of oxidation of metals (characterized by a non-volatile reaction product) and catalytic surface reactions (featuring volatile reaction products). In part I, a brief survey of oxide formation on metals is presented; in a future paper the field of catalysis will be examined in terms of thin film studies. Here it is of importance to distinguish between reactions on continuous thin film substrates and reactions on particulate deposits. In the latter case, the influence of the size and structure of small metallic clusters (10–100 Å) on reaction chemistry can play a decisive role. Small particle-gas interactions also affect the nucleation, growth and sintering processes of thin films. It is shown that various combinations of UHV and high resolution electron microscopy techniques, which include in situ experimentation, can provide the appropriate tools for studying “ångström particle chemistry”." @default.
- W2044354328 created "2016-06-24" @default.
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- W2044354328 date "1976-08-01" @default.
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- W2044354328 title "The interaction of small particles and thin films of metals with gases I. A brief review of the early stages of oxide formation" @default.
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- W2044354328 doi "https://doi.org/10.1016/0040-6090(76)90534-4" @default.
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