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• W2044355881 abstract "Formation behavior and photo-oxidation abilities of nanostructured TiO2 powders were investigated through a direct crystallization from aqueous TiOCl2 solutions containing various metal chlorides at 100 °C. The obtained TiO2 powders without any additives and those with Ni2+, Fe3+ and Nb5+ ions added, which have a similar positive ionic radius to Ti4+, were mainly crystallized with rutile phase, whereas those with Al3+ and Zr4+ ions added, which have a quite different positive ionic radius, were mainly crystallized with anatase phase. On the other hand, the secondary particles in the TiO2 powder consisted of acicular and spherical primary particles, corresponding to rutile and anatase phases, respectively. From these results, it seems that the positive ionic radius of the additives would affect phase formation as well as morphology of TiO2 precipitates. Among the TiO2 powders prepared, Ni-added powder, which consisted mainly of rutile phase with a small amount of anatase phase, showed excellent photocatalytic ability in decomposition of 4-chlorophenol." @default.
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• W2044355881 date "2005-12-13" @default.
• W2044355881 modified "2023-09-27" @default.
• W2044355881 title "Phase transition control of nanostructured TiO₂powders with additions of various metal chlorides" @default.
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• W2044355881 doi "https://doi.org/10.1088/0964-1726/15/1/012" @default.
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