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- W2044356906 abstract "The adsorption and decomposition on polycrystalline Rh of (methylcyclopentadienyl) (1,5-cyclooctadiene) iridium, (MeCp)Ir(COD), has been studied by temperature-programmed desorption (TPD) using time-of-flight mass spectrometry and Auger electron spectroscopy. During early stages of dosing at 100 K there is partial decomposition of (MeCp)Ir(COD) and, in subsequent TPD, only H2 desorbs. For higher doses, (MeCp)Ir(COD) and H2, but no hydrocarbons, desorb. The H2 evolves in several saturable peaks reflecting stepwise C–H bond breaking. In isothermal reaction spectroscopy involving dosing between 350 and 750 K, desorbing products include hydrocarbons with intensities varying with temperature and dosing time. Total sticking probabilities (St) are unity on clean Rh but decrease as deposition products accumulate. Above 750 K the decomposition reaction continues even when the Rh surface is completely covered with precursor decomposition products." @default.
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- W2044356906 date "2001-09-01" @default.
- W2044356906 modified "2023-09-27" @default.
- W2044356906 title "Adsorption and decomposition of (methylcyclopentadienyl) (1,5-cyclooctadiene) iridium on Rh" @default.
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- W2044356906 doi "https://doi.org/10.1116/1.1399322" @default.
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