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- W2044361851 endingPage "908" @default.
- W2044361851 startingPage "879" @default.
- W2044361851 abstract "The syntheses and unique chemical properties of metalladithiolene rings (especially in [CpM(S2C2R1R2)]-type complexes) found by our research group are reviewed. The constructions of metalladithiolene rings by one-pot reaction among [CpM(CO)n], alkyne, and elemental sulfur and by the reaction between [CpM(CO)n] and sulfur-containing heterocyclic compounds are described. Several ionic and radical substitution reactions are presented. The substitutions by carbon-centered and sulfur-centered radicals occur in the metalladithiolene rings. Benzoyloxy-substitution by dibenzoyl peroxide (BPO) and succinimido-substitution by N-halosuccinimides (NXS) proceed via ionic mechanisms induced by the heterolysis of BPO and NXS in the interaction with the lone pair electrons at the sulfur atoms. These substitutions are due to the aromatic character of the metalladithiolene rings. The unique addition reactions due to the unsaturated character of the metalladithiolene rings are also described. Diazo compounds and azides reac..." @default.
- W2044361851 created "2016-06-24" @default.
- W2044361851 creator A5012171799 @default.
- W2044361851 creator A5025172993 @default.
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- W2044361851 date "1999-05-01" @default.
- W2044361851 modified "2023-10-16" @default.
- W2044361851 title "Synthesis and Chemical Properties of Metalladithiolene and Metalladithiazole Rings. Unique Reactions Due to Coexistence of Aromaticity and Unsaturation" @default.
- W2044361851 cites W130429811 @default.
- W2044361851 cites W1457429939 @default.
- W2044361851 cites W1582727934 @default.
- W2044361851 cites W1809969529 @default.
- W2044361851 cites W1964122471 @default.
- W2044361851 cites W1966606654 @default.
- W2044361851 cites W1972299735 @default.
- W2044361851 cites W1972847312 @default.
- W2044361851 cites W1974794315 @default.
- W2044361851 cites W1982833426 @default.
- W2044361851 cites W1983266706 @default.
- W2044361851 cites W1986722960 @default.
- W2044361851 cites W1991556851 @default.
- W2044361851 cites W1992503522 @default.
- W2044361851 cites W1992530355 @default.
- W2044361851 cites W1994395973 @default.
- W2044361851 cites W1998653403 @default.
- W2044361851 cites W1999006771 @default.
- W2044361851 cites W2009108863 @default.
- W2044361851 cites W2010456900 @default.
- W2044361851 cites W2011291686 @default.
- W2044361851 cites W2015470213 @default.
- W2044361851 cites W2019223509 @default.
- W2044361851 cites W2020638747 @default.
- W2044361851 cites W2022991536 @default.
- W2044361851 cites W2026176132 @default.
- W2044361851 cites W2028766181 @default.
- W2044361851 cites W2030593683 @default.
- W2044361851 cites W2030821116 @default.
- W2044361851 cites W2033343478 @default.
- W2044361851 cites W2035483544 @default.
- W2044361851 cites W2043202639 @default.
- W2044361851 cites W2043855451 @default.
- W2044361851 cites W2049293988 @default.
- W2044361851 cites W2049340236 @default.
- W2044361851 cites W2052920172 @default.
- W2044361851 cites W2053308215 @default.
- W2044361851 cites W2054425156 @default.
- W2044361851 cites W2054524324 @default.
- W2044361851 cites W2055899359 @default.
- W2044361851 cites W2058352994 @default.
- W2044361851 cites W2058686589 @default.
- W2044361851 cites W2061542972 @default.
- W2044361851 cites W2061611466 @default.
- W2044361851 cites W2061879045 @default.
- W2044361851 cites W2063208885 @default.
- W2044361851 cites W2063613842 @default.
- W2044361851 cites W2064195483 @default.
- W2044361851 cites W2065666124 @default.
- W2044361851 cites W2065926732 @default.
- W2044361851 cites W2066153861 @default.
- W2044361851 cites W2066774972 @default.
- W2044361851 cites W2070486278 @default.
- W2044361851 cites W2070532423 @default.
- W2044361851 cites W2073451133 @default.
- W2044361851 cites W2077255841 @default.
- W2044361851 cites W2077269139 @default.
- W2044361851 cites W2080462594 @default.
- W2044361851 cites W2082546651 @default.
- W2044361851 cites W2082977104 @default.
- W2044361851 cites W2086145085 @default.
- W2044361851 cites W2087185752 @default.
- W2044361851 cites W2087351161 @default.
- W2044361851 cites W2087655557 @default.
- W2044361851 cites W2095090819 @default.
- W2044361851 cites W2095264340 @default.
- W2044361851 cites W2119260038 @default.
- W2044361851 cites W2142014110 @default.
- W2044361851 cites W2148067637 @default.
- W2044361851 cites W2313535374 @default.
- W2044361851 cites W2314977971 @default.
- W2044361851 cites W2315821208 @default.
- W2044361851 cites W2320296621 @default.
- W2044361851 cites W2323082388 @default.
- W2044361851 cites W2329146555 @default.
- W2044361851 cites W2332355425 @default.
- W2044361851 cites W2332589679 @default.
- W2044361851 cites W2333440825 @default.
- W2044361851 cites W2395171649 @default.
- W2044361851 cites W2520507159 @default.
- W2044361851 cites W2949768561 @default.
- W2044361851 cites W2953071536 @default.
- W2044361851 cites W1988860276 @default.
- W2044361851 doi "https://doi.org/10.1246/bcsj.72.879" @default.
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