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- W2044372130 abstract "The effect of intraparticle diffusion in artificial membranes on the kinetic behavior of immobilized enzymes has been considered theoretically in terms of an effectiveness factor. When the immobilized enxymes obey a Michaelis-Menten relationship, an approximate equation is proposed for the effectiveness factor. For a substrate inhibited enzymatic reaction, the effectiveness factor may exceed unity and display multiple steady-state behavior. Thus, the over-all rate of reaction in the artificial membrane is faster in this case than that when the substrate concentration in the interior is at the same as that at the exterior surface. In the case of a product inhibited enzymatic reaction, the effectiveness factor is always less than that which corresponds to a Michaelis-Menten relationship. On a étudié théoriquement, en fonction d'un facteur d'efficacité, l'effet que produit la diffusion entre particules dans les membranes artificielles sur le comportement cinétique d'enzymes immobilisées. Lorsque les enzymes immobilisées obéissent à une relation de Michaëlis et Menten, on propose une équation d'approximation pour le facteur d'efficacité. Dans le cas d'une réaction enzymatique inhibée par le substrat, le facteur d'efficacité peut ětre plus grand que 1 et indiquer un comportement de régimes permanents multiples; aussi, la vitesse globale de réaction dans la membrane artificielle est-elle plus considérable dans ce cas que lorsque la concentration du substrat à la surface intérieure est la měme que celle qu'on note à la surface extérieure. Dans le cas d'une réaction enzymatique inhibée par un produit, le facteur d'efficacité est toujours moindre que celui qui correspond à une relation de Michaëlis et Menten." @default.
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- W2044372130 date "1972-04-01" @default.
- W2044372130 modified "2023-09-30" @default.
- W2044372130 title "Effectiveness factors for immobilized-enzyme reactions" @default.
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- W2044372130 doi "https://doi.org/10.1002/cjce.5450500204" @default.
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