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- W2044377890 abstract "The efficiency and selectivity of Cu-catalyzed allylic acetoxylation of alkene in different solvent systems is improved by the presence of different metallic salts in the reaction medium. The methodology is particularly well employed for the direct allylic acetoxylation of Δ 5 -steroids at 7-position, for which the resulting acetoxylated product obtained was exclusively α-isomer. Excellent yield was achieved (up to 90%) under optimized conditions, while significantly reducing the costs and environmental hazards and increasing the yield as compared to the other previously reported methods." @default.
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- W2044377890 date "2010-12-01" @default.
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- W2044377890 title "Direct Cu-Catalyzed Allylic Acetoxylation of Δ5-Steroids at 7-Position" @default.
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- W2044377890 doi "https://doi.org/10.1002/jccs.201000183" @default.
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