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- W2044395251 abstract "$^{59}$Co NMR spectra in oriented powders of Na$_{0.35}$CoO$_{2}$ and in its hydrated superconducting phase (HSC) Na$_{0.35}$CoO$_{2}$,1.3H$_{2}$O reveal a single electronic Co state with identical $T$ independent NMR shift tensor. These phases differ markedly from Na$_{0.7}$CoO$_{2}$, in which we resolve 3 types of Co sites. The large T variation of their spin susceptibilities $chi ^{s}$ and the anisotropy of the orbital susceptibility $chi ^{orb}$ allow us to conclude that charge disproportionation occurs, in a non magnetic Co$^{3+}$ and two magnetic sites with about 0.3 and 0.7 holes in the $t_{2g}$ multiplet. The data are consistent with those for the single Co site in the anhydrous and HSC phase assuming the expected Co$^{3.65+}$ charge." @default.
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- W2044395251 date "2005-06-20" @default.
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- W2044395251 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mmultiscripts><mml:mi>Co</mml:mi><mml:mprescripts /><mml:none /><mml:mn>59</mml:mn></mml:mmultiscripts></mml:math>NMR Study of the Co States in Superconducting and Anhydrous Cobaltates" @default.
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- W2044395251 doi "https://doi.org/10.1103/physrevlett.94.247602" @default.
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