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- W2044395620 abstract "Two series of 2-methyl-2-nitrosopropane and nitrosobenzene complexes of platinum(II) have been synthesized including: {PtCl3[(CH3)3C(NO)]}−K+ (I), [PtCl3(C6H5NO)]−K+(II); various trans- {PtCl2[(CH3)3C(NO)]L} complexes with L various pyridines (III (Z)), nitrosobenzene (IV), and 2-methyl-2-nitrosopropane (V); various trans-[PtCl2(C6H5NO)L] complexes with L various pyridines (VI (Z)) and nitrosobenzene (VII); trans and cis isomers of [PtCl2−(C6H5NO)(PR3)] complexes (VIII–XI). The X-ray structure of V, which is the first determined for a platinum(II)—nitrosoalkane complex, establishes its trans configuration and the N-coordination of 2-methyl-2-nitrosopropane to the metal. In complexes III (Z), change from 2,4,6-trimethyl- to 4-nitro-pyridine increases the NO bond strength of 2-methyl-2-nitrosopropane, but this is not significant in the case of the nitrosobenzene complexes VI (Z). Both X-ray and IR data favour nitrosoalkyl- and nitrosoaryl-platinum rather than platinum nitroxide structures and imply a small back donation from platinum(II) to the nitroso ligands. The nitroso compounds appear to have a π-accepting ability smaller than that of ethylene and larger than that of the pyridines." @default.
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- W2044395620 date "1978-11-01" @default.
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- W2044395620 title "2-methyl-2-nitrosopropane and nitrosobenzene as nitrogen-bonded platinum(II) ligands. Molecular structure of {PtCl2[(CH3)3C(NO)]2}" @default.
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- W2044395620 doi "https://doi.org/10.1016/s0022-328x(00)92381-7" @default.
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