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- W2044416616 abstract "A tunable polysiloxane thin-film electrolyte for all-solid-state lithium-ion batteries was developed. The polysiloxane was synthesized by hydrosilylation of polymethylhydrosiloxane with cyclic [(allyloxy)methyl]ethylene ester carbonic acid and vinyl tris(2-methoxyethoxy)silane. 1H NMR spectroscopy and gel-permeation chromatography demonstrated that the bifunctional groups of the cyclic propylene carbonate (PC) and combed poly(ethylene oxide) (PEO) were well grafted on the polysiloxane. At PC/PEO=6:4, the polysiloxane-based electrolyte had an ionic conductivity of 1.55×10−4 and 1.50×10−3 S cm−1 at 25 and 100 °C, respectively. The LiFePO4/Li batteries fabricated with the thin-film electrolyte presented excellent cycling performance in the temperature range from 25 to 100 °C with an initial discharge capacity at a rate of 1 C of 88.2 and 140 mA h g−1 at 25 and 100 °C, respectively." @default.
- W2044416616 created "2016-06-24" @default.
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- W2044416616 date "2014-05-02" @default.
- W2044416616 modified "2023-09-28" @default.
- W2044416616 title "Tuning Thin-Film Electrolyte for Lithium Battery by Grafting Cyclic Carbonate and Combed Poly(ethylene oxide) on Polysiloxane" @default.
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- W2044416616 doi "https://doi.org/10.1002/cssc.201400113" @default.
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