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- W2044419152 abstract "A stable E1cb intermediate, β-cyanoethyl anion (1β), has been synthesized in the gas phase at room temperature under thermal conditions via the fluoride-induced desilylation of 3-(trimethylsilyl)propionitrile. The reactivity and thermodynamic properties of this ion are reported. The cyano group is found to lower the proton affinity of 1β by 29 ± 6 kcal/mol, which represents a particularly large substituent effect. High-level ab initio and density functional calculations have been carried out on 1β and several related species. The computational results are compared to each other, and their accuracy is evaluated." @default.
- W2044419152 created "2016-06-24" @default.
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- W2044419152 date "1996-01-01" @default.
- W2044419152 modified "2023-10-18" @default.
- W2044419152 title "β-Cyanoethyl Anion: Lusus Naturae" @default.
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- W2044419152 doi "https://doi.org/10.1021/ja953796o" @default.
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