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• W2044432937 abstract "Association energies ΔGt in chloroform, in part also in carbon tetrachloride, were determined by NMR titrations of suitably substituted nucleosides and several synthetic analogues. Based on these and on many literature data, two simple free energy increments were derived describing the ΔGt values of 58 complexes within 1.8 kJ mol-1. With chloroform as solvent the increment for the primary interaction between donor and acceptor is 7.9 kJ mol-1, for the secondary one 2.9 kJ mol-1, irrespective of whether the latter is attractive or repulsive. Addition of only 1% methanol to CCl4 led to a decrease in association constants by a factor of 25. Calorimetric titrations of G-C nucleoside derivatives in CCl4 showed substantial contributions from G dimers, in line with NMR titrations, and surprisingly small decreases in entropy. Preliminary NOE measurements allowed us to single out some of the possible association modes; they are also in line with expected self- and triple-association modes of the nucleobases. These modes are generally in accord with nucleobase associations predicted by MM calculations in the literature, which in turn agree with predictions based solely on the increments derived in the present work." @default.
• W2044432937 created "2016-06-24" @default.
• W2044432937 creator A5018731114 @default.
• W2044432937 creator A5031732487 @default.
• W2044432937 date "1996-11-01" @default.
• W2044432937 modified "2023-10-11" @default.
• W2044432937 title "A General Scheme Based on Empirical Increments for the Prediction of Hydrogen-Bond Associations of Nucleobases and of Synthetic Host–Guest complexes" @default.
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• W2044432937 doi "https://doi.org/10.1002/chem.19960021118" @default.
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