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• W2044442020 abstract "The reactions of alkyl isocyanides (RNC) and aryl isocyanides (ArNC) with the rhenium halides K2ReX6 (X = Br or I) and Re3X9 (X = Cl, Br or I) have been investigated. When the K2Rex6 salts are treated with neat isocyanide at room temperature, or with isocyanide ligands in polar solvents under reflux conditions, then the homoleptic isocyanide cations [Re(CNR)6]+ or [Re(CNAr)6]+, are isolated. Under less forcing conditions, various rhenium(III) and rhenium(I) species, e.g. [Re(CNCMe3)5I2]+ and Re(CNAr)5I, which may be considered as intermediates on the way to the formation of the homoleptic species, can be obtained. The rhenium(I) complexes Re(CNAr)5I3, which are believed to contain the coordinated triiodide ligand, have also been isolated and characterized. One route to these complexes is through the reaction of Re(CNAr)5I with I2. Reactions of the trinuclear halides Re3X9 (X = Cl, Br or I) with alkyl isocyanides at room temperature are found, in all instances, to provide adducts of the type Re3X9(CNR)3. Under reflux conditions, Re3Cl9 and Re3Cl9(PEtPh2)3 react with Me3CNC to fom products of cluster disruption, viz. [Re(CNCMe3)6]+ and [Re(CNCMe3)4(PEtPh2)2]+, respectively. The spectroscopic and electrochemical properties of complexes derived in this study are reported. These results are compared with those reported previously by Freni et al." @default.
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• W2044442020 date "1983-10-01" @default.
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• W2044442020 title "The reactions of K2ReX6 (X = Br OR I) and Re3X9 (X = Cl, Br OR I) with alkyl and aryl isocyanides" @default.
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• W2044442020 doi "https://doi.org/10.1016/s0022-328x(00)99328-8" @default.
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