Matches in SemOpenAlex for { <https://semopenalex.org/work/W2044450562> ?p ?o ?g. }
- W2044450562 endingPage "2303" @default.
- W2044450562 startingPage "2291" @default.
- W2044450562 abstract "The use of tetravalent cerium alkoxides, nitrates, and triflates was studied as a direct route to [CeIV(carbene)] complexes. Protonolysis reactions between 1H-imidazolium- or imidazoline (=4,5-dihydro-1H-imidazole)-containing alkoxide proligands HL (L=OCMe2CH2[1-C(NCHCHNiPr)]) and HLS (LS=OCMe2CH2[1-C(NCH2CH2NiPr)]) and CeIV tert-butoxide, triflate, and nitrate compounds were studied to target [CeIV(N-heterocyclic carbene)] complexes (of unsaturated and saturated carbenes, resp.). Instead, tetravalent cerium imidazolium [(OtBu)3Ce(μ-OtBu)2(μ-HL)Ce(OtBu)3], or imidazolinium adducts [(OtBu)3Ce(μ-OtBu)2(μ-HLS)Ce(OtBu)3] were isolated. However, the salt metathesis of cerium triflate with KL provided a simple route to [CeL4], which was significantly improved if an external oxidant, benzoquinone, was included in the mixture to maintain oxidation-state integrity. Likewise, the salt metathesis of cerium triiodide with KL and added benzoquinone provided a straightforward route to [CeL4]." @default.
- W2044450562 created "2016-06-24" @default.
- W2044450562 creator A5004965975 @default.
- W2044450562 creator A5007777131 @default.
- W2044450562 creator A5009618910 @default.
- W2044450562 creator A5029385341 @default.
- W2044450562 date "2009-11-01" @default.
- W2044450562 modified "2023-09-25" @default.
- W2044450562 title "Organometallic Cerium Complexes from Tetravalent Coordination Complexes" @default.
- W2044450562 cites W1821032334 @default.
- W2044450562 cites W1910447395 @default.
- W2044450562 cites W1964414898 @default.
- W2044450562 cites W1965133191 @default.
- W2044450562 cites W1969473376 @default.
- W2044450562 cites W1974780956 @default.
- W2044450562 cites W1977421085 @default.
- W2044450562 cites W1982157638 @default.
- W2044450562 cites W1983983182 @default.
- W2044450562 cites W1993682216 @default.
- W2044450562 cites W1993989681 @default.
- W2044450562 cites W1995865584 @default.
- W2044450562 cites W1996123385 @default.
- W2044450562 cites W2005075414 @default.
- W2044450562 cites W2013299343 @default.
- W2044450562 cites W2016886630 @default.
- W2044450562 cites W2019522907 @default.
- W2044450562 cites W2022435656 @default.
- W2044450562 cites W2024075609 @default.
- W2044450562 cites W2036103209 @default.
- W2044450562 cites W2039975551 @default.
- W2044450562 cites W2040609139 @default.
- W2044450562 cites W2043214131 @default.
- W2044450562 cites W2056280217 @default.
- W2044450562 cites W2058882476 @default.
- W2044450562 cites W2061465994 @default.
- W2044450562 cites W2069966030 @default.
- W2044450562 cites W2074528021 @default.
- W2044450562 cites W2075747149 @default.
- W2044450562 cites W2080297075 @default.
- W2044450562 cites W2080584068 @default.
- W2044450562 cites W2084043287 @default.
- W2044450562 cites W2086810407 @default.
- W2044450562 cites W2090863402 @default.
- W2044450562 cites W2093918451 @default.
- W2044450562 cites W2094506444 @default.
- W2044450562 cites W2100960275 @default.
- W2044450562 cites W2104057453 @default.
- W2044450562 cites W2115009250 @default.
- W2044450562 cites W2128179591 @default.
- W2044450562 cites W2129183887 @default.
- W2044450562 cites W2146703825 @default.
- W2044450562 cites W2157853748 @default.
- W2044450562 cites W2164437923 @default.
- W2044450562 cites W2949350526 @default.
- W2044450562 cites W2950845055 @default.
- W2044450562 cites W3005283929 @default.
- W2044450562 cites W3024946645 @default.
- W2044450562 cites W4211110382 @default.
- W2044450562 doi "https://doi.org/10.1002/hlca.200900152" @default.
- W2044450562 hasPublicationYear "2009" @default.
- W2044450562 type Work @default.
- W2044450562 sameAs 2044450562 @default.
- W2044450562 citedByCount "49" @default.
- W2044450562 countsByYear W20444505622012 @default.
- W2044450562 countsByYear W20444505622013 @default.
- W2044450562 countsByYear W20444505622014 @default.
- W2044450562 countsByYear W20444505622015 @default.
- W2044450562 countsByYear W20444505622017 @default.
- W2044450562 countsByYear W20444505622018 @default.
- W2044450562 countsByYear W20444505622019 @default.
- W2044450562 countsByYear W20444505622020 @default.
- W2044450562 countsByYear W20444505622021 @default.
- W2044450562 countsByYear W20444505622022 @default.
- W2044450562 crossrefType "journal-article" @default.
- W2044450562 hasAuthorship W2044450562A5004965975 @default.
- W2044450562 hasAuthorship W2044450562A5007777131 @default.
- W2044450562 hasAuthorship W2044450562A5009618910 @default.
- W2044450562 hasAuthorship W2044450562A5029385341 @default.
- W2044450562 hasConcept C118629725 @default.
- W2044450562 hasConcept C145148216 @default.
- W2044450562 hasConcept C153914509 @default.
- W2044450562 hasConcept C154881586 @default.
- W2044450562 hasConcept C155647269 @default.
- W2044450562 hasConcept C161790260 @default.
- W2044450562 hasConcept C178790620 @default.
- W2044450562 hasConcept C185592680 @default.
- W2044450562 hasConcept C188027245 @default.
- W2044450562 hasConcept C21774173 @default.
- W2044450562 hasConcept C2777164566 @default.
- W2044450562 hasConcept C2777598222 @default.
- W2044450562 hasConcept C2778591166 @default.
- W2044450562 hasConcept C2778839380 @default.
- W2044450562 hasConcept C2779588249 @default.
- W2044450562 hasConcept C2780874372 @default.
- W2044450562 hasConcept C44138296 @default.
- W2044450562 hasConcept C44228677 @default.
- W2044450562 hasConcept C521977710 @default.
- W2044450562 hasConcept C523597863 @default.