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- W2044460222 abstract "The new ether-bridged dipyridyl ligand 1,2-bis[4-(pyridin-3-yl)phenoxy]ethane (L) has been used to synthesize three isostructural centrosymmetric binuclear Hg(II) macrocycles, namely bis{μ-1,2-bis[4-(pyridin-3-yl)phenoxy]ethane-κ(2)N:N'}bis[dichloridomercury(II)], [Hg(2)Cl(4)(C(24)H(20)N(2)O(2))(2)], and the bromido, [Hg(2)Br(4)(C(24)H(20)N(2)O(2))(2)], and iodido, [Hg(2)I(4)(C(24)H(20)N(2)O(2))(2)], analogues. The Hg atoms adopt a highly distorted tetrahedral coordination environment consisting of two halides and two pyridine N-donor atoms from two bridging ligands. In the solid state, the macrocycles form two-dimensional sheets in the bc plane through noncovalent Hg...X and X...X (X = Cl, Br and I) interactions." @default.
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- W2044460222 date "2012-05-12" @default.
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- W2044460222 title "The structures of three Hg<sub>2</sub><i>X</i><sub>4</sub><i>L</i><sub>2</sub>macrocycles {<i>X</i>= Cl, Br and I, and<i>L</i>= 1,2-bis[4-(pyridin-3-yl)phenoxy]ethane} assembled from ether-bridged dipyridyl ligands" @default.
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- W2044460222 doi "https://doi.org/10.1107/s0108270112019075" @default.
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