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- W2044461363 abstract "The gas permeation properties of the microporous glassy ladder polymer PIM-1 are reported for hydrocarbon/hydrogen mixtures. PIM-1 is more permeable to hydrocarbon vapors than to hydrogen, a behavior similar to that of the microporous linear-chain poly(1-trimethylsilyl-1-propyne) [PTMSP]. For a 2 vol.% n-butane/98 vol.% hydrogen feed mixture, PIM-1 has a mixed-gas n-butane permeability of 4000 Barrer combined with an n-butane/hydrogen selectivity of 27. An increase in n-butane feed concentration leads to an increase in n-butane permeability, but has only a minor effect on the hydrogen permeability. As a result, the n-butane/hydrogen selectivity increases from 27 to 51 as the feed n-butane concentration increases from 2 to 7.3 vol.%. Because of its excellent mixed-gas hydrocarbon/hydrogen selectivity and high permeability, PIM-1 could find use as a novel membrane material in petrochemical applications, such as hydrogen recovery from fluid catalytic cracker off-gases." @default.
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- W2044461363 date "2009-08-01" @default.
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- W2044461363 title "Hydrocarbon/hydrogen mixed-gas permeation properties of PIM-1, an amorphous microporous spirobisindane polymer" @default.
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- W2044461363 doi "https://doi.org/10.1016/j.memsci.2009.04.021" @default.
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