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• W2044480932 abstract "Abstract Investigations of the species produced in pulsed-electron irradiation of alcoholic solutions of transition metal β-diketones have shown them to be reduction products, formed by expulsion of a ligand anion from the transient molecular anion produced in the primary reaction of the solvated electron with the metal chelate. This is consistent with the gas phase chemistry. The stabilities of the molecular anions in solution tend to decrease with increasing electronegativity of the metal chelate for Cr and Co compounds, an observation which is consistent with reported mass spectral fragmentations and with Quasi-Equilibrium Theory predictions." @default.
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• W2044480932 date "1986-01-01" @default.
• W2044480932 modified "2023-09-23" @default.
• W2044480932 title "Pulse radiolysis studies of transition metal beta-diketones—I. Products of electron attachment reactions in solution" @default.
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• W2044480932 doi "https://doi.org/10.1016/1359-0197(86)90129-3" @default.
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