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- W2044494291 abstract "The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under more forcing conditions, products of the further hydrolysis of 6 are obtained. Acetolysis in acetic acid gives the benzyl acetates derived from both N- and O-substituents. With potassium tert-butoxide, the major path is abstraction of an O-benzyl hydrogen followed by fragmentation to the aldehyde and the benzyldiazotate ion. Possible mechanisms for the formation of the products are discussed." @default.
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- W2044494291 date "1992-01-01" @default.
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- W2044494291 title "N-nitrosohydroxylamines I. Acetolysis and acid-catalyzed hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines. Reaction with potassium t-butoxide" @default.
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- W2044494291 doi "https://doi.org/10.1016/s0040-4020(01)89037-2" @default.
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