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- W2044495598 abstract "Abstract The macrocyclic complex (2,3:9,10-dibenzo- 5,7,1 2,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca- 2,4,6,9,11,13-hexaenato(2−)- k4N)nickel(II), [Ni(Bzo2Me4[14]hexaenatoN4)] reacts with cyanogen under mild conditions to give addition-insertion to the methine CH group. The two resulting complexes are characterized by one or two cyanoimino methyl C(NH)CN substituents, from which HCN can be easily released to give the corresponding cyano derivatives. The mono cyano complex [Ni(Bzo2(CN)Me4 [14]hexaenatoN4)] crystallizes in the monoclinic system (space group P21/n) and has a saddle-shaped structure, in which the benzene and β-diiminato groups are tilted in opposite directions, with respect to the plane defined by the four nitrogen and the nickel atoms (CN bond distance 1.141(14) A)." @default.
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- W2044495598 date "1989-05-01" @default.
- W2044495598 modified "2023-10-03" @default.
- W2044495598 title "Reactivity of the macrocyclic complex [Ni(C22H22N4)] toward cyanogen" @default.
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