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- W2044507747 abstract "Abstract Magnetic field treated perfluorosulfonate ionomer (PFSI) membranes (M-PMs) with improved through-plane proton conductivity are facilely fabricated though solvent casting of PFSI/Fe3O4 nanocomposite dispersion without any third additive under magnetic field followed by discarding the Fe3O4 nanoparticles. In the PFSI/Fe3O4 nanocomposite membrane, Fe3O4 nanoparticles are clearly uniaxially aligned by magnetic field. Subsequently, M-PMs are obtained by removing Fe3O4 from the nanocomposite membranes to eliminate the negative effect of Fe3O4 on proton conducting. The effect of magnetic field treatment on M-PMs' performance is investigated by both in- and through-plane proton conductivity. The results demonstrate that the through-plane proton conductivity of the M-PMs prepared from PFSI/Fe3O4 nanocomposite membrane with optimized Fe3O4 content is enhanced, while the in-plane proton conductivity is reduced compared to the pristine PFSI membrane, which indicate through-plane anisotropic phenomenon of proton conducting in the membranes. Such magnetic field treated PFSI membranes exhibit good appropriateness for using in electrochemical applications, for example fuel cells." @default.
- W2044507747 created "2016-06-24" @default.
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- W2044507747 date "2012-12-01" @default.
- W2044507747 modified "2023-10-16" @default.
- W2044507747 title "Perfluorosulfonate ionomer membranes with improved through-plane proton conductivity fabricated under magnetic field" @default.
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- W2044507747 doi "https://doi.org/10.1016/j.memsci.2012.08.023" @default.
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