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• W2044508102 abstract "Abstract VT 1 H NMR spectroscopy proved that a non‐dissociative and reversible mesomerization process links the tetranuclear indium(III) complexes meso ‐(Δ,Δ,Λ,Λ)( P , P , M , M )‐ 3 and meso ‐(Λ,Λ,Δ,Δ)( M , M , P , P )‐ 3′ . During this process four tandem Bailar twists, resulting in the (Δ)/(Λ) isomerization at the indium centers, and the ( P )/( M ) inversion of the four coordinating face‐centered, helical ligands (L 3 ) 3– are involved. In addition, gas‐phase DFT calculations (B3LYP/LANL2DZp) revealed a C 1 ‐symmetric transition state (+21.9 kcal mol –1 ) for the mesomerization mechanism which connects 3 and 3′ ." @default.
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• W2044508102 date "2010-06-23" @default.
• W2044508102 modified "2023-09-26" @default.
• W2044508102 title "Mesomerization of <i>S</i>₄‐Symmetric Tetrahedral Chelate Complex [In₄(L³)₄]: First‐Time Monitored by Temperature‐Dependent ¹H NMR Spectroscopy" @default.
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• W2044508102 doi "https://doi.org/10.1002/ejic.201000295" @default.
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