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• W2044532202 abstract "In a continuing study on discovery of more potent derivatives of sinomenine (1), a clinically available alkaloid for rheumatoid arthritis (RA) treatment, oxidation of sinomenine provided two unique stereoisomers, disinomenines 2 and 3. The structure of 3 was determined by MS, NMR, and X-ray analysis. The formation of 2 and 3 via oxidation of sinomenine by potassium permanganate (KMnO4) exhibited a pH-dependent stereoselectivity. The bioassay results using human synovial sarcoma cells (SW982) showed that 2 inhibited, while 3 stimulated, IL-6 production." @default.
• W2044532202 created "2016-06-24" @default.
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• W2044532202 date "2008-07-23" @default.
• W2044532202 modified "2023-09-30" @default.
• W2044532202 title "pH-Dependent, Stereoselective Dimerization of Sinomenine" @default.
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• W2044532202 doi "https://doi.org/10.1021/ol801403k" @default.
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