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- W2044596918 abstract "New polydentate open structure ligands H3L1 and H3L2 were synthesized by the condensation of 2,6-diformyl-4-tert-butylphenol and corresponding N-R-o-phenylenediamines (R = Ac and R = Boc). Treating of the ligands with copper trimethylacetate leads to binuclear copper complexes with dissimilar Cu2O2 cores, the structures of which were solved by X-ray diffraction analysis. The electrochemical properties of both complexes were studied; the observed redox transitions were assigned to specific redox-active sites of the molecule. These assignments were confirmed by DFT calculations of the electronic structure of binuclear complexes. Both complexes exhibit antiferromagnetic behaviour, as confirmed by variable-temperature magnetic studies." @default.
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- W2044596918 date "2008-05-01" @default.
- W2044596918 modified "2023-09-28" @default.
- W2044596918 title "Influence of ligands’ peripheral substituents on the structure, magnetochemical and electrochemical behaviour of complexes containing a Cu2O2 butterfly core" @default.
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- W2044596918 doi "https://doi.org/10.1016/j.ica.2007.10.020" @default.
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