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• W2044650037 abstract "β-Cyclodextrin (β-CD) was modified with poly(N-isopropylacrylamide) (PIPA, Mn = 2.5 × 103) or poly(ethylene glycol) (PEG, Mn = 5.15 × 103) chains (PIPA−β-CD or PEG−β-CD, respectively). In aqueous solutions of PIPA−β-CD and PEG−β-CD, an inclusion of 2-anilino-6-naphthalenesulfonic acid (2,6-ANS) into a cavity of the modified cyclodextrin increased the fluorescence intensity similarly to a free β-CD−2,6-ANS system. The association constants for 2,6-ANS−PIPA-β-CD and 2,6-ANS−PEG−β-CD systems evaluated were, however, slightly smaller than that for the free β-CD−2,6-ANS system, due to a steric hindrance by the polymer chains on the rim of CD. The PIPA−β-CD and PEG−β-CD could be easily dissolved in a tetrahydrofuran−phosphate buffer (M/30, pH 7.2) mixture (99:1), and the fluorescence intensity of 2,6-ANS in this medium was decreased by the presence of PIPA−β-CD and PEG−β-CD. A similar tendency was observed in the case of PEG−β-CD dissolved in a 1,4-dioxane−buffer mixture (99:1). This phenomenon might be attributed to the inclusion of 2,6-ANS in the less nonpolar environment of the cavity of CD−polymer conjugates than that of bulk solution (tetrahydrofuran−buffer and 1,4-dioxane−buffer, 99:1), which is consistent with the fact that the peak positions of both fluorescence spectra of 2,6-ANS and 8-anilino-1-naphthalenesulfonic acid (1,8-ANS) and electronic spectra of p-tert-butylphenol in aqueous β-CD solution were similar to those in polar organic solvents such as glycerol." @default.
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• W2044650037 date "1998-06-25" @default.
• W2044650037 modified "2023-10-18" @default.
• W2044650037 title "Inclusional Complexation by Cyclodextrin−Polymer Conjugates in Organic Solvents" @default.
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• W2044650037 doi "https://doi.org/10.1021/ma9803739" @default.
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