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- W2044656449 abstract "Abstract Rotational correlation times ( τ c ) of two pairs of small solutes, CpM(CO) 3 and M 2 (CO) 10 (M = Mn, Re), are determined in various viscous alkane solutions by narrow-band IR pump broad-band IR probe spectroscopy. By choosing these pairs of molecules, which are significantly different in mass but almost identical in volume, shape and in their expected interactions with solvents, we isolate the effects of mass on τ c . The effect of mass was observed clearly for these pairs of solute tracers, with heavier substitutions leading to larger τ c values. In the case of the CpM(CO) 3 pair, in which the moments of inertia do not change much, the effect of mass was seen in the τ c vs. solvent viscosity plot as result of larger slope for heavier substitution, with no clear change in the intercept. For the M 2 (CO) 10 pair, in which the moments of inertia change significantly, this mass effect can be observed through changes in both the slope and intercept." @default.
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- W2044656449 date "2013-08-01" @default.
- W2044656449 modified "2023-09-23" @default.
- W2044656449 title "Mass effect on rotational diffusion of small solutes in solution" @default.
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- W2044656449 doi "https://doi.org/10.1016/j.chemphys.2012.10.004" @default.
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