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- W2044657871 endingPage "1331" @default.
- W2044657871 startingPage "1315" @default.
- W2044657871 abstract "The substitution of hydrogen by fluorine in organic compounds usually results in drastic changes in their properties. For isocyanides, for which fluorinated examples have only recently become available in preparative quantities, this substitution leads to a significantly increased reactivity and a tendency to polymerize, which, on one hand, makes their handling more difficult. On the other hand, this high reactivity makes the fluorinated isocyanides useful building blocks for the synthesis of compounds like N-trimethylformamide. Energetically favorable π* orbitals bestow excellent π-acceptor properties towards low-valent transition metal complexes, especially on the ligand trifluoromethyl isocyanide. The pronounced tendency of this ligand to bridge two metal atoms enables the formation of structural types that are not accessible with other π-acceptor ligands. Thus it was possible to prepare [(Os3(CO)11(μ2-CNCF3)2] (a) derivative of the hypothetical [Os(CO)13]) which may be considered as a model for an associative mechanism of ligand substitution at carbonyl clusters. In contrast to the well-studied chemistry of trifluoromethyl isocyanide, that of the few other known fluorinated isocyanides is only now receiving attention. In particular the only recently synthesized trifluorovinyl isocyanide promises a rich chemistry as a result of its difunctionality." @default.
- W2044657871 created "2016-06-24" @default.
- W2044657871 creator A5060787706 @default.
- W2044657871 date "1994-07-18" @default.
- W2044657871 modified "2023-10-09" @default.
- W2044657871 title "Fluorinated Isocyanides?More than Ligands with Unusual Properties" @default.
- W2044657871 cites W1008621380 @default.
- W2044657871 cites W1468194517 @default.
- W2044657871 cites W1488141875 @default.
- W2044657871 cites W1517459457 @default.
- W2044657871 cites W1560491399 @default.
- W2044657871 cites W1623960843 @default.
- W2044657871 cites W1964440755 @default.
- W2044657871 cites W1966929595 @default.
- W2044657871 cites W1968267262 @default.
- W2044657871 cites W1968363358 @default.
- W2044657871 cites W1968858161 @default.
- W2044657871 cites W1969121588 @default.
- W2044657871 cites W1970128856 @default.
- W2044657871 cites W1970409169 @default.
- W2044657871 cites W1970490444 @default.
- W2044657871 cites W1971654638 @default.
- W2044657871 cites W1973258241 @default.
- W2044657871 cites W1974567286 @default.
- W2044657871 cites W1976258099 @default.
- W2044657871 cites W197643260 @default.
- W2044657871 cites W1977212995 @default.
- W2044657871 cites W1978588569 @default.
- W2044657871 cites W1979090696 @default.
- W2044657871 cites W1979876595 @default.
- W2044657871 cites W1981469476 @default.
- W2044657871 cites W1981490496 @default.
- W2044657871 cites W1981913962 @default.
- W2044657871 cites W1982101185 @default.
- W2044657871 cites W1983088879 @default.
- W2044657871 cites W1983999318 @default.
- W2044657871 cites W1984443047 @default.
- W2044657871 cites W1988047541 @default.
- W2044657871 cites W1988981382 @default.
- W2044657871 cites W1992402327 @default.
- W2044657871 cites W1993764067 @default.
- W2044657871 cites W1994068251 @default.
- W2044657871 cites W1996061427 @default.
- W2044657871 cites W1996371679 @default.
- W2044657871 cites W1997553140 @default.
- W2044657871 cites W1997607053 @default.
- W2044657871 cites W1998342132 @default.
- W2044657871 cites W1998995779 @default.
- W2044657871 cites W1999651958 @default.
- W2044657871 cites W2002400515 @default.
- W2044657871 cites W2002583034 @default.
- W2044657871 cites W2002649540 @default.
- W2044657871 cites W2003157661 @default.
- W2044657871 cites W2005773052 @default.
- W2044657871 cites W2009297863 @default.
- W2044657871 cites W2010827803 @default.
- W2044657871 cites W2010971493 @default.
- W2044657871 cites W2011500965 @default.
- W2044657871 cites W2012157520 @default.
- W2044657871 cites W2013779870 @default.
- W2044657871 cites W2014804612 @default.
- W2044657871 cites W2016330779 @default.
- W2044657871 cites W2017084603 @default.
- W2044657871 cites W2018013676 @default.
- W2044657871 cites W2018702845 @default.
- W2044657871 cites W2020297216 @default.
- W2044657871 cites W2021429287 @default.
- W2044657871 cites W2024207966 @default.
- W2044657871 cites W2028102473 @default.
- W2044657871 cites W2034512878 @default.
- W2044657871 cites W2037652501 @default.
- W2044657871 cites W2039468612 @default.
- W2044657871 cites W2040650285 @default.
- W2044657871 cites W2040935744 @default.
- W2044657871 cites W2044555110 @default.
- W2044657871 cites W2045849088 @default.
- W2044657871 cites W2046175730 @default.
- W2044657871 cites W2048596575 @default.
- W2044657871 cites W2048652684 @default.
- W2044657871 cites W2052172809 @default.
- W2044657871 cites W2053842276 @default.
- W2044657871 cites W2054509150 @default.
- W2044657871 cites W2056312522 @default.
- W2044657871 cites W2056424206 @default.
- W2044657871 cites W2058394126 @default.
- W2044657871 cites W2058590295 @default.
- W2044657871 cites W2059683151 @default.
- W2044657871 cites W2061430487 @default.
- W2044657871 cites W2061542592 @default.
- W2044657871 cites W2061861031 @default.
- W2044657871 cites W2062900849 @default.
- W2044657871 cites W2063113033 @default.
- W2044657871 cites W2064305903 @default.
- W2044657871 cites W2065075607 @default.
- W2044657871 cites W2066804165 @default.
- W2044657871 cites W2066829750 @default.
- W2044657871 cites W2067251260 @default.
- W2044657871 cites W2069821491 @default.