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- W2044692765 abstract "Anion adsorption on the aluminum oxide, gibbsite, was investigated as a function of solution pH (3-11) and equilibrium solution Mo (3.13, 31.3, or 313 μmol/L), P (96.9 μmol/L), or S (156 μmol/L) concentration. Adsorption of all three anions decreased with increasing pH. Electrophoretic mobility measurements indicated a downward shift in point of zero charge, indicative of an inner-sphere adsorption mechanism for all three anions. The constant capacitance model, having an inner-sphere adsorption mechanism, was able to describe Mo and P adsorption; whereas the triple-layer model with an outer-sphere adsorption mechanism was used to describe S adsorption. Competitive adsorption experiments showed a reduction of Mo adsorption at a Mo/P ratio of 1:30 and 1:300 but no reduction at a Mo/S ratio of 1:52 and 1:520. These concentrations are realistic of natural systems where Mo is found in much lesser concentrations than P or S. Using surface complexation constants from single-ion systems, the triple-layer model predicted that even elevated S concentrations did not affect Mo adsorption. The constant capacitance model was able to predict the competitive effect of P on Mo adsorption semiquantitatively." @default.
- W2044692765 created "2016-06-24" @default.
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- W2044692765 date "2010-03-01" @default.
- W2044692765 modified "2023-10-07" @default.
- W2044692765 title "Competitive Adsorption of Molybdenum in the Presence of Phosphorus or Sulfur on Gibbsite" @default.
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- W2044692765 doi "https://doi.org/10.1097/ss.0b013e3181d3462f" @default.
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