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- W2044702421 abstract "CF3 radicals were generated by the photolysis of perfluoroacetic anhydride. In the presence of pentafluorobenzene, the CF3 radicals react according to the following mechanism: It was found that the addition reaction (3) becomes reversible above ca. 453 K. The addition rate parameters have been revised and they satisfactorily agree with those reported previously. At temperatures higher than 593 K, only true H-abstraction occurs. The rate constant kH for reaction (5) is given by: where θ = 2.303 RT kJmol−1 and kc is the rate constant for combination of CF3 radicals. The reactions of CF3 with benzene and pentafluorobenzene are compared." @default.
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- W2044702421 date "1991-05-01" @default.
- W2044702421 modified "2023-09-25" @default.
- W2044702421 title "The gas phase reaction of CF3 radicals with C6F5H in the temperature range 373-658 K" @default.
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- W2044702421 doi "https://doi.org/10.1002/kin.550230502" @default.
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