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- W2044706533 abstract "The preparation and characterization of the novel perfluorinated sulfone (CF2SO2)3 (1) has been achieved via static fluorination of the potassium salt of (CH2SO2)3. In addition to this product, the highly interesting by-products SO2(CF2SO2F)2 (2), CF2(SO2CF3)2 (3), CF3SO2CF2SO2F (4), CF2(SO2F)2 (5) and CF3SO2CF2SO2CF2SO2F (6) were also prepared. Infrared, NMR and mass spectra are presented in order to support the assigned structures; only compound 5 is known. The gas-phase molecular structure of 1 has been studied by electron-diffraction methods. Assuming C2 overall symmetry with equal axial and equatorial S=O and C-F bond lengths, nine geometric parameters were required to describe the structure of 1. The six-membered ring possesses a chair conformation with C3 symmetry and the following ring parameters: C-F= 1.338(4), O=S = 1.418(2), C-S =1.866(4) Å and angles 〈CSC=100.2(7), 〈FCF=109.2(7), 〈OSO=125.9(14)°." @default.
- W2044706533 created "2016-06-24" @default.
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- W2044706533 date "1994-04-01" @default.
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- W2044706533 title "A new cyclic fluorinated trisulfone (CF2SO2)3 and fluorinated derivatives: SO2(CF2SO2F)2, CF2(SO2CF3)2, CF3SO2CF2SO2F, CF2(SO2F)2 and CF3SO2CF2SO2CF2SO2F" @default.
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- W2044706533 doi "https://doi.org/10.1016/0022-1139(93)02925-5" @default.
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