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- W2044707901 abstract "Abstract Gas‐phase reactions between 13 CO 2 and C 18 O 2 and a series of carbonyl metallate ions [Metal(CO) x ] − with x=3, 4 for the metals chromium, manganese, iron and also x=2 for iron, have ben examined at low pressures by Fourier‐transform ion cyclotron resonance mass spectrometry. while the 16‐and 17‐electron ions [Mn(CO) 4 ] − and [Fe(CO) 4 ] − were unreactive, both ligand displacement and oxidative reactions have been identified for the other 13‐, 14‐ and 15‐electron metal‐ion systems as a consequences of Metal‐C, O 13 and 18 OC cleavages in [(CO) x . Metal. η 2 ‐OCO] − intermidiates." @default.
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- W2044707901 date "1992-03-01" @default.
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- W2044707901 title "Gas-phase chemistry of first transition series carbonyl metallate ions, [Metal(CO)x]−: Reactions with13C- and18O-Labelled carbon dioxide. A Fourier-transform ion cyclotron resonance study" @default.
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- W2044707901 doi "https://doi.org/10.1002/rcm.1290060314" @default.
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