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• W2044713048 abstract "A reversible electrochemical behavior is demonstrated on a specially prepared redox-functionalized H-Si(100) surface, obtained via an extra-mild grafting procedure from vinylferrocene. The results of a detailed XPS and electrochemical characterization of the resulting hybrid are reported and discussed to propose it as a reference system for high-quality electroactive monolayers on Si. The investigated ferrocene derivative bears a functional group suitable for a mild route to covalent anchoring on Si, which is based on a photoinduced reaction with visible light under an inert atmosphere. Electrochemical reversibility is shown by sharp symmetric voltammograms on freshly prepared p-Si electrodes. Anodic oxide growth is responsible for the progressive degradation of the electrochemical response. Still, fast electron transfer to the surface redox species is maintained during several thousands cycles." @default.
• W2044713048 created "2016-06-24" @default.
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• W2044713048 date "2006-03-24" @default.
• W2044713048 modified "2023-09-26" @default.
• W2044713048 title "Electrochemical Reversibility of Vinylferrocene Monolayers Covalently Attached on H-Terminated p-Si(100)" @default.
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• W2044713048 doi "https://doi.org/10.1021/jp056921j" @default.
• W2044713048 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16599512" @default.
• W2044713048 hasPublicationYear "2006" @default.
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