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• W2044741831 abstract "Kinetic parameters for aldose and ketose transformations in the d-glucose-d-mannose-d-fructose system at 27° on aluminate resin and hydroxide resin were obtained. On both resins, hydroxide ion functions as the catalyst for isomerization. By forming a complex with d-fructose, resin-bound aluminate ion stabilizes the ketose and permits high yields (up to 72%) of d-fructose from d-glucose. The effect of temperature on d-glucose-to-d-fructose conversion was studied; lower temperatures give the higher maximum yields. Maltose is converted into maltulose in moderately high yield (63%) at 24° on aluminate resin; higher yields are not possible at this temperature because of a marked tendency for maltulose to undergo elimination of d-glucose at C-4." @default.
• W2044741831 created "2016-06-24" @default.
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• W2044741831 date "1979-10-01" @default.
• W2044741831 modified "2023-10-14" @default.
• W2044741831 title "Complexes of carbohydrates with aluminate ion. Aldose-ketose interconversion on anion-exchange resin (aluminate and hydroxide forms)" @default.
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• W2044741831 doi "https://doi.org/10.1016/s0008-6215(00)84629-7" @default.
• W2044741831 hasPublicationYear "1979" @default.
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