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• W2044742366 endingPage "L598" @default.
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• W2044742366 abstract "Abstract Coverage-dependent adlayer structures of iodine on Au(111) in air or organic solvents obtained by using a high-precision “beetle” — type scanning tunnelling microscope are reported in comparison with those obtained under potential control in aqueous electrochemical environments. The well-known (√3 × √3)R30° structure (ΘI = 0.33) was only observed at the electrochemical interface at low potentials. Instead, two higher coverage adlattices are evident from the present STM images. The first comprises a (5 × √3) structure (ΘI = 0.40), with a pair of iodine rows compressed by 20% in the R30° substrate direction. The second high-coverage phase (ΘI ≈ 0.44) consists of a hexagonal iodine overlayer compressed and rotated a few degrees from the R30° direction, giving rise to a long-range (~ 20 A) corrugation in the STM image. The virtues of quantitative atomic-resolution STM for deducing such complex adiayer structures are pointed out." @default.
• W2044742366 created "2016-06-24" @default.
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• W2044742366 date "1992-08-01" @default.
• W2044742366 modified "2023-09-23" @default.
• W2044742366 title "Iodine adlayer structures on Au(111) as discerned by atomic-resolution scanning tunnelling microscopy: relation to iodide electrochemical adsorption" @default.
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• W2044742366 doi "https://doi.org/10.1016/0039-6028(92)90831-p" @default.
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