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• W2044745060 abstract "Die Organometall-Arsine MAs(CH3)2 [MC5H5(CO)3Mo, C5H5(CO)3W und C5H5(CO)2Fe] reagieren mit Metallcarbonylen M′ CO [M′ Cr(CO)5, Mo(CO)5, W(CO)5, Mn(CO)2C5H5, Fe(CO)4, Fe(CO)(NO)2, Co(CO)2NO und Ni(CO)3] nach üblichen Verfahren unter Bildung der Zweikernkomplexe M  As(CH3)2  M′ (2–4). Bei Umsetzung mit Co(CO)2C5H5 bilden sich unter weiterer CO-Abspaltung direkt arsenverbrückte Komplexe mit Metall-Metall-Bindungen (5a, b). Versuche zur photochemischen Umwandlung der Zweikernkomplexe M  As(CH3)2  M′ in Komplexe mit Metall-Metall-Bindung waren nur für die bereits bekannten Fälle erfolgreich. Organometallic Lewis Bases, XXXII. Preparation of Dinuclear Complexes via Organometal Arsines The organometal arsines M  As(CH3)2 [MC5H5(CO)3Mo, C5H5(CO)3W, C5H5(CO)2Fe] react with metal carbonyls M′ CO [M′Cr(CO)5, Mo(CO)5, W(CO)5, Mn(CO)2C5H5, Fe(CO)4, Fe(CO)(NO)2, Co(CO)2NO and Ni(CO)3] in the usual manner to form the dinuclear complexes M  As(CH3)2  M′ (2–4). Upon reaction with Co(CO)2C5H5 further CO elimination occurs with direct formation of arsenic-bridged complexes with metal-metal bonds (5a, b). Attempts to convert the dinuclear complexes M  As(CH3)2  M′ photochemically into complexes with metal-metal bonds were successful only in the cases already known." @default.
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• W2044745060 date "1977-12-01" @default.
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• W2044745060 title "Metallorganische Lewis‐Basen, XXXII. Darstellung von Zweikernkomplexen über Organometall‐Arsine" @default.
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• W2044745060 doi "https://doi.org/10.1002/cber.19771101222" @default.
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