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- W2044745971 endingPage "1614" @default.
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- W2044745971 abstract "The preparation and resolution of the two hexadentate Co(III) complexes containing unsymmetrical edta-type ligands, [Co(ed3ap)]− (A) and [Co(u-eddadp)]− (B) (ed3ap = ethylenediamine-N,N,N′-triacetate-N′-3-propionate ion; u-eddadp = ethylenediamine-N-diacetate-N′-di-3-propionate ion) have been reexamined. The X-ray data are reported for the Λ-(−)546-trans(O)5-Li[Co(ed3ap)]·H2O for which the same (Λ) absolute configuration was predicted from the CD sign pattern of the lowest energy band. The complex crystallizes in the space group P21 (#4) of the monoclinic crystal system with a = 6.523(4), b = 15.025(7), c = 7.464(3) Å, β = 105.40(4)°, and Z = 2. The conformations of the chelate rings are found to be envelope for the glycinates and skew-boat (half-chair) for the β-alaninate ring. Structural parameters and strain analysis of [Co(edta-type)]− chelates are discussed in relation to the structure of the ligand and octahedral distortion of complexes. The CD and IR (carboxylate region) spectra of complexes A and B are also discussed." @default.
- W2044745971 created "2016-06-24" @default.
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- W2044745971 date "1998-07-01" @default.
- W2044745971 modified "2023-10-11" @default.
- W2044745971 title "Synthesis and Characterization of Hexadentate Cobalt(III) Complexes with New edta-Type Ligands Part 5. Structure and Absolute Configuration of the<i>trans</i>(O<sub>5</sub>)(−)<sub>546</sub>-Isomer of Lithium (Ethylenediamine-<i>N</i>,<i>N</i>,<i>N</i>′-triacetato-<i>N</i>′-3-propionato)cobaltate(III) Monohydrate, (−)<sub>546</sub>-<i>trans</i>(O<sub>5</sub>)-Li[Co(ed3ap)]·H<sub>2</sub>O. Strain Analysis of [Co(edta-Type)]<sup>−</sup>Chelates in Relation to Their Octahedral Distortion" @default.
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- W2044745971 doi "https://doi.org/10.1246/bcsj.71.1605" @default.
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