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• W2044751008 abstract "A good linear correlation has been presented for the absorption maxima of solvated electrons in 17 different solvents and 13 solvent mixtures versus the absorption maxima of the iodide ion in the same medium. It is concluded that the electronic transitions of the solvated electron parallel those of the charge-transfer-to-solvent (CTTS) transitions of iodide ion. The absence of a direct correlation between νmax of solvated electrons and the static dielectric constant of the medium is emphasized. Based on the CTTS scale of iodide, the optical transitions of esolv− in other solvents (e.g., alkyl nitriles, phosphates and carbonates) can be predicted." @default.
• W2044751008 created "2016-06-24" @default.
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• W2044751008 date "1974-04-01" @default.
• W2044751008 modified "2023-09-27" @default.
• W2044751008 title "Correlation of the CTTS solvent scale with νmax of the solvated electron. Prediction of band maxima" @default.
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• W2044751008 doi "https://doi.org/10.1016/0009-2614(74)85355-8" @default.
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