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- W2044763805 abstract "A broadly applicable synthesis of chiral 2- or 2,4-substituted cyclopent-2-enones has been developed by combining asymmetric iridium-catalyzed allylic alkylation reactions and ruthenium-catalyzed ring-closing metathesis. Enantiomeric excesses (ee values) in the range of 95-99 % ee have been achieved. This method offers a straightforward access to biologically active prostaglandins of the PGA type. As an example, an enantioselective synthesis of the prostaglandin-analogue 13,14-dihydro-15-deoxy-Delta(7)-prostaglandin-A1-methyl ester (TEI-9826) has been carried out. Furthermore, the carbonucleoside 2'-methylcarbovir has been prepared from O-protected 4-hydroxymethyl-2-methyl-cyclopent-2-enone by Pd-catalyzed allylic amination." @default.
- W2044763805 created "2016-06-24" @default.
- W2044763805 creator A5000409977 @default.
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- W2044763805 date "2008-07-21" @default.
- W2044763805 modified "2023-10-17" @default.
- W2044763805 title "Preparation of 2,4-Disubstituted Cyclopentenones by Enantioselective Iridium-Catalyzed Allylic Alkylation: Synthesis of 2′-Methylcarbovir and<i>TEI-9826</i>" @default.
- W2044763805 cites W1968249260 @default.
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- W2044763805 cites W1992485607 @default.
- W2044763805 cites W1992933344 @default.
- W2044763805 cites W1992951110 @default.
- W2044763805 cites W1996736435 @default.
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- W2044763805 doi "https://doi.org/10.1002/chem.200800495" @default.
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