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- W2044764265 abstract "Production of useful building block materials with high value-added from natural resources is becoming increasingly relevant due to depletion of fossil-derived feedstock. Metathesis of recycled vegetable oils with satisfactory activity is viewed as challenging but possible and attractive route for production of these building blocks. A novel rhenium based catalyst supported on mesoporous alumina modified by zinc chloride was developed, characterized and tested for metathesis of methyloleate, a model molecule for the triglycerides and oils. The catalyst showed a high activity and a good selectivity equivalent to that of homogeneous second generation Grubbs catalyst where a conversion of 92.0% after 30 min of reaction and a total metathesis product yield of 86.7% with 52% attributed to the desired metathesis products were attained. This paper highlighted also the effect of methyltrioxorhenium (MTO) loading on the metathesis activity where 3% MTO loading revealed to be optimum." @default.
- W2044764265 created "2016-06-24" @default.
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- W2044764265 date "2013-08-01" @default.
- W2044764265 modified "2023-10-07" @default.
- W2044764265 title "Functionalized value-added products via metathesis of methyloleate over methyltrioxorhenium supported on ZnCl2-promoted mesoporous alumina" @default.
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- W2044764265 doi "https://doi.org/10.1016/j.fuel.2012.10.040" @default.
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