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• W2044767004 abstract "An H-like band, blue-shifted from an absorption maximum of a monomer band, has been formed in merocyanine–arachidic acid mixed Langmuir–Blodgett (LB) films by adding n-alkane species of different chain lengths (CH3(CH2)n−2CH3, n=18 and 28) as a third component. In each ternary system, the blue-shifted band is prominent or is accompanied by a J-band depending on the preparation conditions. The absorption spectra A‖ and A⊥ were measured using a normal incident of linearly polarized light with the electric vector either parallel or perpendicular to the dipping direction, respectively. The results of surface pressure–area isotherm measurements have indicated that the alkane species remaining in the monolayer and filling empty spaces near surface-active molecules act as the trigger molecules to induce the H-like aggregates. Comparing these results with the predictions from the theory of flow orientation and the extended dipole model, it is suggested that the present blue-shifted H-like band is of an H-aggregate rather than a dimer." @default.
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• W2044767004 date "1998-08-01" @default.
• W2044767004 modified "2023-09-27" @default.
• W2044767004 title "Control of aggregate formation in merocyanine Langmuir–Blodgett films" @default.
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• W2044767004 doi "https://doi.org/10.1016/s0040-6090(98)00666-x" @default.
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