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- W2044769612 abstract "The voltammetric behaviour of aniline and some of its N-alkylated derivatives at a carbon-paste (Nujol/graphite) electrode is examined. The N-alkylated anilines, in contrast to aniline, are accumulated at the electrode by a combined adsorption/extraction process. The organic bases are determined in the rane 10−7−2×10−6 M after a 2-min preconcentration period by differential pulse voltammetry; N,N-dimethylaniline can be determined in the presence of excess of aniline (10−5 M) by using medium-exchange. The voltammetric method is used for evaluation of the distribution ratios of the organic bases in the Nujol/aqueous buffer system. The enhancement of the voltammetric signal of each base is correlated with the respective distribution ratio." @default.
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- W2044769612 date "1988-01-01" @default.
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- W2044769612 title "Voltammetric determination of N-alkylated anilines by adsorption/extraction at a carbon-paste electrode" @default.
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- W2044769612 doi "https://doi.org/10.1016/s0003-2670(00)86359-x" @default.
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