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- W2044771610 abstract "Reaction of four esters of α-L-arabinofuranosyl bromide with 1,5-diazabicyclo-[5.4.0]undec-5-ene causes elimination of hydrogen bromide. In the case of the tris-(p-nitrobenzoate), only degradation products were observed, but from the other three esters, 1,4-anhydro-L-erythro-pent-1-enitol compounds were isolated. These compounds isomerise readily on standing in non-hydroxylic solvents to give 3-deoxypent-2-enofuranoses, and simultaneously lose benzoic acid to give furans. In ethanolic solution, both the 1,4-anhydropent-1-enitol esters and their 3-deoxy-2-enofuranose isomers react at room temperature to give anomeric mixtures of ethyl 3-deoxypent-2-enofuranosides. Compounds in this series are judged to be too reactive to serve generally as satisfactory glycosylating agents." @default.
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- W2044771610 date "1974-12-01" @default.
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- W2044771610 title "Esters of 1,4-anhydro-L-erythro-pent-1-enitol (a furanoid 2-hydroxyglycal)" @default.
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- W2044771610 doi "https://doi.org/10.1016/s0008-6215(00)82344-7" @default.
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