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- W2044803337 abstract "An X-ray bond charge model is presented for the reevaluation of quasiforbidden reflections from InSb and GaAs. The bond charge is assumed to be an additional scattering centre. The matrix atoms remain spherical, but the valence orbitals are reduced by the bond charge amount. The reconstruction of the experimental structure factors measured by Bilderback is established in the same quality as his semiempirical deformation model. Further the position and the form of the bond charge can be deduced with respect to the distance between next neighbours. Ein Bindungsladungsmodell zur Interpretation röntgenographisch gemessener „quasiverbotener”︁ Reflexe in InSb und GaAs wird vorgestellt. Die Bindungsladung wird als zusätzliches Streuzentrum angenommen. Die sphärische Symmetrie der Valenzschalen soll erhalten bleiben, jedoch wird deren Elektronenzahl um den Betrag der Bindungsladung reduziert. Die Rekonstruktion der von Bilderback gemessenen Strukturfaktoren ist in der gleichen Weise möglich wie mit dem von ihm vorgestellten semiempirischen Deformationsmodell. Mit Hilfe dieses Modells kann zusätzlich Form und Ort der Bindungsladung bezüglich der Verbindungslinie nächster Nachbarn angegeben werden." @default.
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- W2044803337 date "1981-01-01" @default.
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- W2044803337 title "X-Ray Bond Charge in GaAs and InSb" @default.
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- W2044803337 doi "https://doi.org/10.1002/pssb.2221030108" @default.
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