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- W2044809904 abstract "Phases and compositions obtained from the molten systems CsPbCl3–CsPbBr3 and CsPbClnBr3–n-CsSnClnBr3–n have been identified and compared with those from the CsSnCl3–CsSnBr3 system. X-Ray powder data are consistent with all of the products being single-phase solid solutions based on the perovskite lattice and in which there is random distribution of Group IV metal and halide ions. 119Sn Mössbauer data for the phases with cubic unit cells are characterised by high chemical shifts and narrow linewidths, indicative of the presence of tin(II) in octahedral sites, I.r. spectra of the cubic phases contain bands assignable to all of the possible stretching modes but only an average bending mode. There are no bands in the Raman spectra of the cubic phases. Colours obtained in the products are discussed in terms of the population of conductance bands by electrons from ns2 orbitals of the Group IV metal ions." @default.
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- W2044809904 date "1973-01-01" @default.
- W2044809904 modified "2023-10-03" @default.
- W2044809904 title "Phases obtained from the frozen molten systems caesium–tin–halide and caesium–lead–halide" @default.
- W2044809904 doi "https://doi.org/10.1039/dt9730001985" @default.
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