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• W2044819975 abstract "Analysis of the Rabin–Panyukov theory of scattering from polyelectrolyte gels shows that the theory predicts an anomalous cross-link density (CD) dependence of amplitude of spatial inhomogeneity in charged polymer networks. By increasing the interaction parameter or by decreasing the degree of ionization, one can pass from a regime in which the calculated structure factor is a monotonically increasing function of CD, to one in which an inflection in the CD dependence is predicted. These theoretical predictions were experimentally verified by light scattering experiments on a series of weakly charged polymer gels of N-isopropylacrylamide-acrylic acid copolymer. The ensemble average scattered intensity, a measure of the spatial inhomogeneity, increased with CD for χ&lt;χc and decreased with CD for χ&gt;χc, where χ and χc are the interaction parameter and the critical value of χ, respectively." @default.
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• W2044819975 date "1997-10-01" @default.
• W2044819975 modified "2023-09-30" @default.
• W2044819975 title "Effect of degree of cross-linking on spatial inhomogeneity in charged gels. I. Theoretical predictions and light scattering study" @default.
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• W2044819975 doi "https://doi.org/10.1063/1.474886" @default.
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