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- W2044820270 abstract "article i nfo Urea and butyrylcholine chloride (BuChCl) biosensors were prepared by adsorption of urease and butyrylcholinesterase (BuChE) on heat-treated zeolite Beta crystals, which were incorporated into membranes deposited on ion-selective field-effect transistor (ISFET) surfaces. The responses, stabili- ties, and use for inhibition analysis of these biosensors were investigated. Different heat treatment procedures changed the amount of Bronsted acid sites without affecting the size, morphology, overall Si/Al ratio, external specific surface area, and the amount of terminal silanol groups in zeolite crystals. Upon zeolite incorporation the enzymatic response so f biosensors towards urea and BuChCl increased up to ~2 and ~5 times, respectively; and correlated with the amount of Bronsted acid sites. All bio- sensors demonstrated high signal reproducibility and stability for both urease and BuChE. The inhibi- tion characteristics of urease and BuChE were also related to the Bronsted acidity. The pore volume and pore size increases measured for the heat-treated samples are very unlikely causes for the im- provements observed in biosenso rs' performance, because ureaseand BuChE are approximately one order of magnitude larger than the resulting zeolite Beta pores. Overall, these results suggest that the zeolites incorporated into the biologically active membrane with enhanced Bronsted acidity can improve the performance of ISFET-based biosensors." @default.
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- W2044820270 date "2012-10-01" @default.
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- W2044820270 title "Investigation of characteristics of urea and butyrylcholine chloride biosensors based on ion-selective field-effect transistors modified by the incorporation of heat-treated zeolite Beta crystals" @default.
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- W2044820270 doi "https://doi.org/10.1016/j.msec.2012.04.071" @default.
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