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• W2044821738 abstract "The rates of formation and dissociation of monocarboxylic complexes of aquocobalt(III) cations with propionic, malonic, and 2-ethylmalonic acids have been measured with the stopped-flow method over a range of concentrations and temperatures in acid perchlorate media at an ionic strength 3.0 M. Although the rate constants for reactions of CoOHaq2+ with neutral ligands cover only a small range, indicating a dissociative mechanism, the associated activation parameters change cooperatively. These variations are discussed in terms of differences in the structure, proton distribution, and rates of water loss in the ion-pair precursors for the different ligands. Similar activation enthalpies of dissociation indicate a common mode of coordination, and the positive activation entropies for dissociation are consistent with a neutral leaving group." @default.
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• W2044821738 creator A5085826439 @default.
• W2044821738 date "2007-06-01" @default.
• W2044821738 modified "2023-10-18" @default.
• W2044821738 title "Kinetics of Formation and Dissociation of Aquocobalt(III) Complexes with Some Carboxylic Acids in Acid Perchlorate Solution†" @default.
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• W2044821738 doi "https://doi.org/10.1021/jp070848a" @default.
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