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- W2044857543 abstract "Abstract The compounds [W(CMe)(CO)2(η-C5H5)] and [Ru(CO)3(cdpe)] (cdpe cis-Ph2PCHCHPPh2) react in tetrahydrofuran at reflux temperatures to give in ca 70% yield the dimetal compound [WRu(μ-σ,η2-CHCH2)(CO)4(cdpe)(η-C5H5)]. The structure of the latter has been established by X-ray diffraction. The WRu bond [2.973(1) A] is spanned by the vinyl group which is σ-bonded to the ruthenium atom (RuC 2.095(5) A) and η2-coordinated to the tungsten (WC 2.209(5) and 2.313(5) A). The two metal atoms are each ligated by two carbonyl groups, but one CO attached to tungsten semi-bridges the metal-metal bond (WCO 169.2(5)°). The cyclopentadienyl group is η5-bonded to the tungsten, and the cis-Ph2PCHCHPPh2 ligand is coordinated to the ruthenium (RuP 2.300(1) and 2.396(1) A)." @default.
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- W2044857543 date "1989-01-01" @default.
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- W2044857543 title "Synthesis and x-ray crystal structure of the tungsten-ruthenium compound [WRu(μ-σ,η2-CHCH2)(CO)4(cis-Ph2PCHCHPPh2)(η-C5H5)]" @default.
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- W2044857543 doi "https://doi.org/10.1016/s0277-5387(00)83833-4" @default.
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