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- W2044919808 abstract "Abstract The low temperature infrared absorption and room temperature laser Raman spectra of polycrystalline Ba(NO 2 ) 2 · H 2 O and its deuterated analogue are studied. The strongly bonded H-atom of the water molecule makes a highly bent H-bond while the weakly bonded H-atom exhibits a slightly bent (or possible bifurcated) bond consistent with recent structural data; the H-bond enthalpies are estimated to be 3.3 and 2.1 KCal mole respectively. The wagging, twisting and rocking modes of the water molecule have been assigned using several well known criteria. The force constants of these modes have also been computed. The librational splittings observed at low temperature are consistent with polarization data, and are being attributed to infrared active factor group components." @default.
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- W2044919808 date "1983-01-01" @default.
- W2044919808 modified "2023-09-23" @default.
- W2044919808 title "Infrared and raman spectra of barium nitrite monohydrate" @default.
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- W2044919808 doi "https://doi.org/10.1016/0022-3697(83)90073-2" @default.
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