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• W2044938032 abstract "From the reaction of MeReO3 with the neutral arylamine C6H5CH2NMe2 and the aryldiamine C6H4(CH2NMe2)2−1,3, have been isolated in good yields the 1/1 adduct complex [MeReO3 · C6H5CH2NMe2], 1, and the 2/1 adduct complex [(MeReO3)2 · C6H4(CH2NMe2)2− 1,3], 2, respectively. The X-ray molecular structure of 2 shows that both rhenium centres have a trigonal bipyramidal geometry and in the axial positions of each rhenium centre are one of the NMe2 units of the aryldiamine ligand and a methyl group. The mono(ortho)-chelated arylaminorhenium trioxide complex [ReO3(C6H4CH2NMe2−2], 3, can be synthesized by a transmetallation reaction of ClReO3 with [ZnC6H4CH2NMe2−22] in a 2:1 molar ratio. In a similar way the bis(ortho)-chelated arylaminorhenium trioxide complex [ReO3C6H3(CH2NMe2)2−2,6], 4, can be synthesized by addition of a mixture of [Li2C6H3(CH2NMe2)2−2,62] and ZnCl2 to ClReO3. Complexes 3 and 4 have been isolated as white solids in 66% and 81% yields respectively. The rhenium centre in complex 4 has a bicapped tetrahedral geometry in which the monoanionic C6H3(CH2NMe2)2−2,6− ligand is pseudo-facially bonded with a characteristic N1-Re-N2 angle of 107.7(3)°, a Re-Cipso bond length of 2.112(11) Å and Re-N1 and Re-N2 bond lengths of 2.518(9) Å and 2.480(8) Å respectively." @default.
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• W2044938032 date "1997-03-01" @default.
• W2044938032 modified "2023-10-16" @default.
• W2044938032 title "Synthesis of methyltrioxorhenium(VII) arylamine complexes and mono- and bis(ortho)-chelated arylaminorhenium(VII) trioxides" @default.
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• W2044938032 doi "https://doi.org/10.1016/s0022-328x(96)06665-x" @default.
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