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- W2044944234 abstract "The rates of addition of 2,4-dinitrobenzenesulphenyl chloride to aliphatic alkenes in acetic acid at 25·0 °C are correlated by the equation, log k/k0=ρ*Σσ*+δΣEs, where log k0=–1·28, ρ*=–2·84, and δ= 0·664. Rates for trans-alkenes were excluded from this correlation as with similar studies involving chlorination and bromination. 2,4-Dinitrobenzenesulphenyl chloride is less selective in its addition reactions than chlorine or bromine and this is attributed to the greater participation by sulphur as a neighbouring group which reduces the effect of electron-releasing groups in the alkene. Steric effects are of relatively greater importance with the sulphenyl halide than with the halogens and this also contributes to the lower selectivity." @default.
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- W2044944234 date "1971-01-01" @default.
- W2044944234 modified "2023-09-25" @default.
- W2044944234 title "Electrophilic additions to alkenes. Part VII. The addition of 2,4-dinitrobenzenesulphenyl chloride to aliphatic alkenes" @default.
- W2044944234 doi "https://doi.org/10.1039/j29710000175" @default.
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